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Journal Articles

Evidence for a difference in the dissociation mechanisms of acetylene (HCCH) and vinylidene (H$$_{2}$$C=C:) from charge inversion mass spectrometry

Hayakawa, Shigeo*; Tomozawa, Koji*; takeuchi, takae*; Arakawa, Kazuo; Morishita, Norio

Physical Chemistry Chemical Physics, 5(11), p.2386 - 2390, 2003/05

 Times Cited Count:15 Percentile:44.34(Chemistry, Physical)

The process of formation of the negative ions in charge inversion mass spectrometry is via near-resonant neutralization followed by spontaneous dissociation, and then endothermic negative ion formation. The intensity of the C$$_{2}$$$$^{-}$$ peak relative to the C$$_{2}$$H$$^{-}$$ peak in these spectra increased with decreasing ionization potential of the targets for both of the isomeric C$$_{2}$$H$$_{2}$$$$^{+}$$ cations. The formation of the C$$_{2}$$$$^{-}$$ anion is proposed to result from the dissociation of excited C$$_{2}$$H$$_{2}$$ neutrals into C$$_{2}$$ and H$$_{2}$$. The dependence on target species of the intensities of C$$_{2}$$$$^{-}$$ peak relative to the C$$_{2}$$H$$^{-}$$ peak for HCCH and H$$_{2}$$C=C: cannot be rationalized by the internal energy of the excited C$$_{2}$$H$$_{2}$$ neutrals. The differences indicate that the isomeric C$$_{2}$$H$$_{2}$$ neutrals dissociate into C$$_{2}$$H and H prior to 1,2-hydrogen atom migration.

Journal Articles

A New technique to study the dissociation of energy-selected neutral intermediates

Hayakawa, Shigeo*; Harada, Kengo*; Watanabe, Nobuaki*; Arakawa, Kazuo; Morishita, Norio

International Journal of Mass Spectrometry, 202(1-3), p.A1 - A7, 2000/10

 Times Cited Count:16 Percentile:60.02(Physics, Atomic, Molecular & Chemical)

no abstracts in English

Journal Articles

Study of dissociation of neutral intermediates using charge inversion mass spectrometry

Hayakawa, Shigeo*; Harada, Kengo*; Arakawa, Kazuo; Morishita, Norio

Journal of Chemical Physics, 112(19), p.8432 - 8435, 2000/05

 Times Cited Count:19 Percentile:50.78(Chemistry, Physical)

no abstracts in English

Journal Articles

Laser-induced fluorescence of 1,3,5-trimethoxybenzene radical cation in solution at room temperature

Ichinose, Yuji; *; Kawanishi, Shunichi; *; *

Journal of Physical Chemistry A, 103(40), p.7923 - 7926, 1999/10

 Times Cited Count:22 Percentile:70.26(Chemistry, Physical)

no abstracts in English

Journal Articles

Definitive evidence for the existence of a long-lived vinylidene radical cation, H$$_{2}$$C=C$$^{+}$$

Hayakawa, Shigeo*; *; Arakawa, Kazuo; Morishita, Norio

Journal of Chemical Physics, 110(6-8), p.2745 - 2748, 1999/02

 Times Cited Count:21 Percentile:55.26(Chemistry, Physical)

no abstracts in English

Journal Articles

Generation of polyphenylene radical cations and their cosensitization ability in the 9,10-dicyanoanthracene-sensitized photochemical chain reactions of 1,2-bis(4-methoxyphenyl) cyclopropane

*; Ichinose, Yuji; *; Sasuga, Tsuneo; *; *

J. Org. Chem., 63(10), p.3204 - 3212, 1998/00

 Times Cited Count:24 Percentile:63.07(Chemistry, Organic)

no abstracts in English

Journal Articles

Laser-induced chemical modification of the surface of fluoropolymers

Kawanishi, Shunichi; Ichinose, Yuji

Reza Kenkyu, 24(7), p.780 - 786, 1996/07

no abstracts in English

Journal Articles

Excimer laser-induced surface reaction of fluoropolymers with liquid water

Ichinose, Yuji; Kawanishi, Shunichi

Macromolecules, 29, p.4155 - 4157, 1996/00

 Times Cited Count:10 Percentile:44.72(Polymer Science)

no abstracts in English

Journal Articles

Photochemical surface modification of poly(hexafluoropropylene-co-tetrafluoroethylene)(FEP) film with triethylamine

Ichinose, Yuji; *; Kawanishi, Shunichi; *; *

Chemistry Letters, 0(10), p.943 - 944, 1995/00

no abstracts in English

Journal Articles

Discrimination of C$$_{3}$$H$$_{4+}$$ isomeric ions by charge inversion mass spectrometry using an alkali metal target

*; *; Arakawa, Kazuo; Morishita, Norio; *

Int. J. Mass Spectrom. Ion Process, 151, p.89 - 95, 1995/00

no abstracts in English

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